• haohan甲苯二异氰酸酯TDI异构体分析专用色谱柱30m

    详细信息

     品牌:haohan  型号:30m  加工定制:是  
     测量范围:ppm  测量对象:甲苯二异氰酸酯TDI异构体  控温范围:200 ℃ 
     尺寸:3000 mm 重量:0.02 Kg 环氧乙烷:乙缩醛  
     粗苯:三苯  二甲苯:变压器油  多氯联苯:脂肪酸甲酯  
     3%Dexil-300/Chromoso:二氧化碳    

     

    TDI (toluene diisocyanate) is one of the commonly used polyisocyanates, while polyisocyanates are polyurethane (PU) materials and important base materials. Commonly used TDI in the polyurethane industry is a mixture of 2,4-TDI and 2,6-TDI isomers, including three commonly used grades: TDI-80/20, TDI-100 and TDI-65/35. The preceding figures indicate the amount of 2,4-TDI in the composition. For example, 80 in TDI-80/20 represents 80% 2,4-TDI and 20% 2,6-TDI; 100 in TDI-100 represents essentially 2,4-TDI %), 2,6-TDI isomers are few. Mainly used in the production of flexible polyurethane foam and polyurethane elastomers, coatings, adhesives and so on.
    3. A method of capillary gas chromatography (GC) for the analysis of toluene diisocyanate was proposed. The separation capacity of toluene diisocyanate isomers was determined by coating the column with an elastic quartz capillary column, using a special GC stationary phase, an aryl carboxylate liquid crystal and a cyclodextrin derivative. The effects of flow rate and temperature on the separation were investigated, and the optimum GC stationary phase for toluene diisocyanate was selected. Separation of tolylene diisocyanate isomers using a special capillary gas chromatographic stationary phase. The method is simple, rapid, accurate and suitable for industrial analysis and environmental monitoring of toluene diisocyanate isomers.

       TDI(甲苯二异氰酸酯)是常用的多异氰酸酯的一种,而多异氰酸酯是聚氨酯(PU)材料和重要基础原料。聚氨酯工业常用的TDI是2,4-TDI和2,6-TDI两种异构体的混合物,包括3种常用的牌号:TDI-80/20,TDI-100和TDI-65/35。前面的数字表示组成中2,4-TDI的含量。比如TDI-80/20中的80表示其组成为80%的2,4-TDI和20%的2,6-TDI;TDI-100中的100表示基本上都是2,4-TDI(约98% ),2,6-TDI的异构体很少。主要用于生产软质聚氨酯泡沫及聚氨酯弹性体、涂料、胶黏剂等。

                寻找分析甲苯二异氰酸酯的毛细管气相色谱方法。选择专用的气相色谱固定液,芳羧酸酯液晶和环糊精衍生物等涂渍成弹性石英毛细管柱,测定它们对甲苯二异氰酸酯异构体的分离能力。考察流速和温度对分离度的影响,选出分析甲苯二异氰酸酯的***佳气相色谱固定相。用专用毛细管气相色谱固定相可较好地对甲苯二异氰酸酯异构体进行分离。本方法简单、快速、准确率高,适合用于工业分析和环境监测甲苯二异氰酸酯异构体。


     

     

     
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